Flavor ingredient regulatory record

4-Decenal

4-Decenal is an aldehyde in the fruity family, FEMA GRAS under FEMA number 3264 (CAS 30390-50-2). Its odor is fruity, green, waxy, cucumber, floral.

FEMA
3264
CAS
30390-50-2
JECFA
326
EU FL
05.096
Formula
C10H18O

GRAS status: FEMA GRAS, publication 5. Recorded by FDA in the Substances Added to Food inventory under CAS 30390-50-2.

Structure

2D structure of 4-Decenal
Structure of 4-Decenal, C10H18O. Drawn from the canonical SMILES.

Identity

IUPAC name dec-4-enal
CAS number 30390-50-2
FEMA number 3264
Molecular formula C10H18O
Molecular weight 154.25 g/mol
SMILES CCCCCC=CCCC=O
InChIKey CWRKZMLUDFBPAO-UHFFFAOYSA-N
PubChem CID 61875
Chemical class Aldehyde
Boiling point -80 °C
Flash point 87 °C

Also known as: 4-decen-1-al, (e)-4-decen-1-al, db-045659, db-054810.

Can 4-Decenal be labeled natural?

4-Decenal occurs in nature, so the label depends on the route: 4-Decenal won from a natural source by a physical, enzymatic or microbiological process is natural flavor in the United States, and synthesized 4-Decenal is artificial. The EU and UK grant the natural claim only to that natural route; Mercosur and Mexico call synthetic material identical-to-natural.

United States
Natural or artificial, by process
European Union and UK
Natural only from natural material
Mercosur and Mexico
Natural or identical-to-natural

How each market defines the classes: natural vs artificial flavor under 21 CFR 101.22.

Regulatory status, with citations

United States

4-Decenal is FEMA GRAS under FEMA number 3264. It is cited in the Code of Federal Regulations at 21 CFR 172.515.

21 CFR 172.515

European Union and United Kingdom

Listed on the Union List of flavouring substances as FL 05.096, Annex I Part A under Regulation (EC) 1334/2008, evaluation status approved (JECFA). The UK retains the same list.

JECFA (WHO / FAO)

JECFA number 326, evaluated at the 51st meeting in 1998. no safety concern at current levels of intake.

JECFA monograph

Other US flags

Not on the California Proposition 65 list.

TSCA Inventory status

A flavor ingredient is also an industrial chemical. 4-Decenal appears on the EPA Toxic Substances Control Act Chemical Substance Inventory under CAS 30390-50-2, where EPA names it 4-Decenal.

Active in US commerce

EPA designates this substance active, so no Notice of Activity Form B is required before manufacturing. What active and inactive mean.

EPA publishes no regulatory flags on this listing. What the flags mean.

From the EPA non-confidential TSCA Inventory, July 2026 release. EPA also maintains a confidential portion it does not publish. Search the Inventory by CAS number.

Odor and taste

Odor: Fruity, green, waxy, cucumber, floral.

Taste: Fresh, fruity, slightly fatty.

Where it is used

4-Decenal is used in beverage, confection, fruit flavors, savory dishes and snacks, typically as a fruity note.

Structurally similar flavor ingredients

Flavor ingredients with a GRAS determination closest to 4-Decenal by structure. Whether one can replace it is a sensory and regulatory call; the reformulation tool works that through.

MaterialFEMASimilarityOccurrence
cis-8-Decenal494599%Not determined
(E)-4-Nonenal430298%In nature
trans-2-Decenal236698%In nature
(E)-4-Undecenal467298%Not determined
trans-Nonenal321394%In nature

More aldehydes in this index

4-Methyl-2-pentenal · Dodec-2-(trans)-enal · 4-Ethylbenzaldehyde · Paraldehyde · Isobutanal propyleneglycol acetal · 2-Methyl-3-(p-isopropylphenyl)propionaldehyde

4-Decenal FAQ

Is 4-Decenal FEMA GRAS?

Yes. The FEMA Expert Panel lists 4-Decenal as GRAS under FEMA number 3264. It is also codified at 21 CFR 172.515.

What are the FEMA and CAS numbers for 4-Decenal?

4-Decenal is FEMA 3264, CAS 30390-50-2. FEMA files it in the fruity flavor category.

Does 4-Decenal count as natural in the US and the EU?

Since 4-Decenal is found in nature, US labeling follows how it was obtained: natural flavor from a natural source and a natural process, artificial when 4-Decenal is synthesized. The EU and UK grant the natural claim only to that natural route; Mercosur and Mexico call synthetic material identical-to-natural.

Is 4-Decenal on the EU Union List?

4-Decenal is on the EU Union List of flavouring substances as FL 05.096 (Annex I Part A) under Regulation 1334/2008.

Has JECFA evaluated 4-Decenal?

Yes. JECFA number 326, evaluated at the 51st meeting in 1998. Conclusion: no safety concern at current levels of intake.

How is 4-Decenal described, and where does it show up?

Flavorists describe 4-Decenal as fruity, green, waxy, cucumber, floral. On the palate it is fresh, fruity, slightly fatty. It is used in beverage, confection, fruit flavors, savory dishes and snacks.

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Guides: What Is FEMA GRAS? · Natural vs artificial · Filing a GRAS notification

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Sources and attribution. The identity and regulatory facts on this page are taken from the FDA Substances Added to Food inventory, a US government record, which lists this substance as 4-DECENAL under CAS 30390-50-2 and carries its FEMA number, its JECFA flavor number. The inventory is searchable at FDA. FDA records its technical effect as flavoring agent or adjuvant.

A FEMA GRAS conclusion is reached by the Expert Panel of the Flavor and Extract Manufacturers Association of the United States, and the FEMA number names that conclusion. FEMA publishes its own entry for this substance in the FEMA Flavor Library, which is the authoritative record of what the Panel decided and is worth reading alongside this page.

Ambrose Compliance is not affiliated with, endorsed by, or sponsored by FEMA. FEMA and FEMA GRAS are used here as identifiers for a published regulatory determination, not as marks of any relationship between FEMA and Ambrose.

About this page. Facts come from the FDA Substances Added to Food inventory, the Code of Federal Regulations, the EPA TSCA Inventory, the EU Union List, JECFA and the Ambrose database, with FEMA's published determination cited where it applies; parts of the text are written by Ambrose AI, which can make mistakes. Check the cited source before relying on anything here. This is not regulatory or legal advice.