Flavor ingredient regulatory record

Benzyl acetate

Benzyl acetate is an ester in the floral family, FEMA GRAS under FEMA number 2135 (CAS 140-11-4). Its odor is floral, fruity, jasmine, pear.

FEMA
2135
CAS
140-11-4
JECFA
23
EU FL
09.014
Formula
C9H10O2
EC
205-399-7

GRAS status: FEMA GRAS, publication 3. Recorded by FDA in the Substances Added to Food inventory under CAS 140-11-4.

Structure

2D structure of Benzyl acetate
Structure of Benzyl acetate, C9H10O2. Drawn from the canonical SMILES.

Identity

IUPAC name benzyl acetate
CAS number 140-11-4
FEMA number 2135
Molecular formula C9H10O2
Molecular weight 150.18 g/mol
SMILES CC(=O)OCc1ccccc1
InChIKey QUKGYYKBILRGFE-UHFFFAOYSA-N
PubChem CID 8785
EC number 205-399-7
FDA UNII 0ECG3V79ZJ
EPA DTXSID DTXSID0020151
Chemical class Ester
Boiling point 213 °C
Flash point 90 °C

Also known as: Acetic acid, phenylmethyl ester, Acetic acid, benzyl ester, Benzyl alcohol, acetate, Benzyl ethanoate, α-Acetoxytoluene, (Acetoxymethyl)benzene, Phenylmethyl acetate, NSC 4550, Jeffsol AG 1705, Jeffsol AG 1700, acetic acid benzyl ester, phenylmethyl acetate.

Can Benzyl acetate be labeled natural?

The process decides for benzyl acetate. It occurs in nature, so a natural-source, natural-process material is natural flavor in the US and synthetic benzyl acetate is artificial. The EU and UK follow the same logic without a middle class; Mercosur and Mexico label synthetic benzyl acetate identical-to-natural.

United States
Natural or artificial, by process
European Union and UK
Natural only from natural material
Mercosur and Mexico
Natural or identical-to-natural

How each market defines the classes: natural vs artificial flavor under 21 CFR 101.22.

Regulatory status, with citations

United States

Benzyl acetate is FEMA GRAS under FEMA number 2135. It is cited in the Code of Federal Regulations at 21 CFR 172.515.

21 CFR 172.515

European Union and United Kingdom

Listed on the Union List of flavouring substances as FL 09.014, Annex I Part A under Regulation (EC) 1334/2008, evaluation status approved (EFSA). The UK retains the same list.

JECFA (WHO / FAO)

JECFA number 23, evaluated at the 46th meeting in 1996. ADI 0 to 5 mg/kg body weight.

JECFA monograph

Other US flags

Not on the California Proposition 65 list.

TSCA Inventory status

A flavor ingredient is also an industrial chemical. Benzyl acetate appears on the EPA Toxic Substances Control Act Chemical Substance Inventory under CAS 140-11-4, where EPA names it Acetic acid, phenylmethyl ester.

Active in US commerce

EPA designates this substance active, so no Notice of Activity Form B is required before manufacturing. What active and inactive mean.

EPA publishes no regulatory flags on this listing. What the flags mean.

From the EPA non-confidential TSCA Inventory, July 2026 release. EPA also maintains a confidential portion it does not publish. Search the Inventory by CAS number.

Odor and taste

Odor: Floral, fruity, jasmine, pear.

Taste: Floral, slightly fruity.

Where it is used

Benzyl acetate is used in jasmine, pear and floral, typically as a floral note.

Structurally similar flavor ingredients

Flavor ingredients with a GRAS determination closest to Benzyl acetate by structure. Whether one can replace it is a sensory and regulatory call; the reformulation tool works that through.

MaterialFEMASimilarityOccurrence
4-Phenyl-3-buten-2-one288184%In nature
4-(p-Tolyl)-2-butanone307483%In nature
Benzyl propionate215074%In nature
alpha-Methylbenzyl acetate268473%In nature
Ethyl phenylacetate245270%In nature

More esters in this index

Linalyl anthranilate · Eugenyl benzoate · Phenethyl salicylate · Phenethyl acetate · Ethyl linalyl ether · (Z)-Hex-3-enyl salicylate

Benzyl acetate FAQ

Is benzyl acetate on the FEMA GRAS list?

It is. FEMA number 2135 covers benzyl acetate. The Code of Federal Regulations lists it at 21 CFR 172.515.

What is the FEMA number for benzyl acetate?

The FEMA number for benzyl acetate is 2135 and its CAS registry number is 140-11-4. Its flavor category is floral.

What is benzyl acetate used for?

Benzyl acetate is described as floral, fruity, jasmine, pear. On the palate it is floral, slightly fruity. It shows up in jasmine, pear and floral.

What did JECFA conclude about benzyl acetate?

JECFA evaluated benzyl acetate at the 46th meeting in 1996 under JECFA number 23.

Is benzyl acetate approved in the EU?

Yes. FL 09.014 is the Union List entry for benzyl acetate, annex I Part A, under Regulation 1334/2008, and the UK keeps the same list.

Is benzyl acetate natural or artificial?

Nature makes benzyl acetate, which is why the US label turns on process. A natural route gives natural flavor; synthesis gives artificial benzyl acetate, same molecule. The EU and UK grant the natural claim only to that natural route; Mercosur and Mexico call synthetic material identical-to-natural.

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Sources and attribution. The identity and regulatory facts on this page are taken from the FDA Substances Added to Food inventory, a US government record, which lists this substance as BENZYL ACETATE under CAS 140-11-4 and carries its FEMA number, its JECFA flavor number and its 21 CFR citations. The inventory is searchable at FDA. FDA records its technical effect as flavoring agent or adjuvant.

A FEMA GRAS conclusion is reached by the Expert Panel of the Flavor and Extract Manufacturers Association of the United States, and the FEMA number names that conclusion. FEMA publishes its own entry for this substance in the FEMA Flavor Library, which is the authoritative record of what the Panel decided and is worth reading alongside this page.

Ambrose Compliance is not affiliated with, endorsed by, or sponsored by FEMA. FEMA and FEMA GRAS are used here as identifiers for a published regulatory determination, not as marks of any relationship between FEMA and Ambrose.

About this page. Facts come from the FDA Substances Added to Food inventory, the Code of Federal Regulations, the EPA TSCA Inventory, the EU Union List, JECFA and the Ambrose database, with FEMA's published determination cited where it applies; parts of the text are written by Ambrose AI, which can make mistakes. Check the cited source before relying on anything here. This is not regulatory or legal advice.