Flavor ingredient regulatory record

2-Methyl-2-pentenoic acid

2-Methyl-2-pentenoic acid is an acid in the fruity family, FEMA GRAS under FEMA number 3195 (CAS 3142-72-1). Its odor is fruity, tangy, citrus, green.

FEMA
3195
CAS
3142-72-1
JECFA
1210
EU FL
08.055
Formula
C6H10O2
EC
221-552-0

GRAS status: FEMA GRAS, publication 4. Recorded by FDA in the Substances Added to Food inventory under CAS 3142-72-1.

Structure

2D structure of 2-Methyl-2-pentenoic acid
Structure of 2-Methyl-2-pentenoic acid, C6H10O2. Drawn from the canonical SMILES.

Identity

IUPAC name 2-methylpent-2-enoic acid
CAS number 3142-72-1
FEMA number 3195
Molecular formula C6H10O2
Molecular weight 114.14 g/mol
SMILES CCC=C(C)C(=O)O
InChIKey JJYWRQLLQAKNAD-UHFFFAOYSA-N
PubChem CID 18458
EC number 221-552-0
Chemical class Acid
Boiling point 74 °C
Flash point 20 °C

Also known as: 2-Pentenoic acid, 2-methyl-, strawberry acid, 2-methylpent-2-en-1-oic acid, 2-methylpent-2-enoic acid, 2-pentenoic acid, 2-methyl-, strawberriff, pentenoic acid, 2-methyl-, methylpent-2-enoic acid, 2-methyl-pent-2-enoic acid, db-003293.

Can 2-Methyl-2-pentenoic acid be labeled natural?

The process decides for 2-Methyl-2-pentenoic acid. It occurs in nature, so a natural-source, natural-process material is natural flavor in the US and synthetic 2-Methyl-2-pentenoic acid is artificial. The EU and UK grant the natural claim only to that natural route; Mercosur and Mexico call synthetic material identical-to-natural.

United States
Natural or artificial, by process
European Union and UK
Natural only from natural material
Mercosur and Mexico
Natural or identical-to-natural

How each market defines the classes: natural vs artificial flavor under 21 CFR 101.22.

Regulatory status, with citations

United States

2-Methyl-2-pentenoic acid is FEMA GRAS under FEMA number 3195. It is cited in the Code of Federal Regulations at 21 CFR 172.515.

21 CFR 172.515

European Union and United Kingdom

Listed on the Union List of flavouring substances as FL 08.055, Annex I Part A under Regulation (EC) 1334/2008, evaluation status approved (EFSA). The UK retains the same list.

JECFA (WHO / FAO)

JECFA number 1210, evaluated at the 61st meeting in 2003. no safety concern at current levels of intake.

JECFA monograph

Other US flags

Not on the California Proposition 65 list.

TSCA Inventory status

A flavor ingredient is also an industrial chemical. 2-Methyl-2-pentenoic acid appears on the EPA Toxic Substances Control Act Chemical Substance Inventory under CAS 3142-72-1, where EPA names it 2-Pentenoic acid, 2-methyl-.

Active in US commerce

EPA designates this substance active, so no Notice of Activity Form B is required before manufacturing. What active and inactive mean.

EPA publishes no regulatory flags on this listing. What the flags mean.

From the EPA non-confidential TSCA Inventory, July 2026 release. EPA also maintains a confidential portion it does not publish. Search the Inventory by CAS number.

Odor and taste

Odor: Fruity, tangy, citrus, green.

Where it is used

2-Methyl-2-pentenoic acid is used in beverage, confection, fruit flavors, sauces and dressings, typically as a fruity note.

Structurally similar flavor ingredients

Flavor ingredients with a GRAS determination closest to 2-Methyl-2-pentenoic acid by structure. Whether one can replace it is a sensory and regulatory call; the reformulation tool works that through.

MaterialFEMASimilarityOccurrence
Methyl-3-pentenoic acid346498%In nature
2-Methylvaleric acid275495%In nature
(E)-2-Pentenoic acid419391%In nature
2-Methyl-4-pentenoic acid351191%In nature
2,4-Dimethyl-2-pentenoic acid314391%In nature

More acids in this index

3-Isopropenyl-6-oxoheptanoic acid · cis- and trans-2-Heptylcyclopropanecarboxylic acid · 3-Methylcrotonic acid · 3-Methylpentanoic acid · 3-Hydroxy-2-oxopropionic acid · Decanedioic acid

2-Methyl-2-pentenoic acid FAQ

Is 2-Methyl-2-pentenoic acid FEMA GRAS?

Yes. The FEMA Expert Panel lists 2-Methyl-2-pentenoic acid as GRAS under FEMA number 3195. The Code of Federal Regulations lists it at 21 CFR 172.515.

What are the FEMA and CAS numbers for 2-Methyl-2-pentenoic acid?

2-Methyl-2-pentenoic acid is FEMA 3195, CAS 3142-72-1. Its flavor category is fruity.

How is 2-Methyl-2-pentenoic acid described, and where does it show up?

Flavorists describe 2-Methyl-2-pentenoic acid as fruity, tangy, citrus, green. It is used in beverage, confection, fruit flavors, sauces and dressings.

What did JECFA conclude about 2-Methyl-2-pentenoic acid?

JECFA evaluated 2-Methyl-2-pentenoic acid at the 61st meeting in 2003 under JECFA number 1210. The panel concluded: no safety concern at current levels of intake.

Is 2-Methyl-2-pentenoic acid on the EU Union List?

Yes. FL 08.055 is the Union List entry for 2-Methyl-2-pentenoic acid, annex I Part A, under Regulation 1334/2008, and the UK keeps the same list.

Does 2-Methyl-2-pentenoic acid count as natural in the US and the EU?

Nature makes 2-Methyl-2-pentenoic acid, which is why the US label turns on process. A natural route gives natural flavor; synthesis gives artificial 2-Methyl-2-pentenoic acid, same molecule. In the EU and UK the natural claim likewise needs the natural route, while Mercosur and Mexico keep a third class, identical-to-natural, for the synthetic material.

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Sources and attribution. The identity and regulatory facts on this page are taken from the FDA Substances Added to Food inventory, a US government record, which lists this substance as 2-METHYL-2-PENTENOIC ACID under CAS 3142-72-1 and carries its FEMA number, its JECFA flavor number. The inventory is searchable at FDA. FDA records its technical effect as flavoring agent or adjuvant.

A FEMA GRAS conclusion is reached by the Expert Panel of the Flavor and Extract Manufacturers Association of the United States, and the FEMA number names that conclusion. FEMA publishes its own entry for this substance in the FEMA Flavor Library, which is the authoritative record of what the Panel decided and is worth reading alongside this page.

Ambrose Compliance is not affiliated with, endorsed by, or sponsored by FEMA. FEMA and FEMA GRAS are used here as identifiers for a published regulatory determination, not as marks of any relationship between FEMA and Ambrose.

About this page. Facts come from the FDA Substances Added to Food inventory, the Code of Federal Regulations, the EPA TSCA Inventory, the EU Union List, JECFA and the Ambrose database, with FEMA's published determination cited where it applies; parts of the text are written by Ambrose AI, which can make mistakes. Check the cited source before relying on anything here. This is not regulatory or legal advice.