Flavor ingredient regulatory record

Ethyl (E)-2-methyl-2-pentenoate

Ethyl (E)-2-methyl-2-pentenoate is an ester in the fruity family, FEMA GRAS under FEMA number 4290 (CAS 1617-40-9). Its odor is sweet, fruity, peach, tropical, estery.

FEMA
4290
CAS
1617-40-9
JECFA
1815
Formula
C8H14O2

GRAS status: FEMA GRAS, publication 23. Recorded by FDA in the Substances Added to Food inventory under CAS 1617-40-9.

Structure

2D structure of Ethyl (E)-2-methyl-2-pentenoate
Structure of Ethyl (E)-2-methyl-2-pentenoate, C8H14O2. Drawn from the canonical SMILES.

Identity

IUPAC name ethyl (E)-2-methylpent-2-enoate
CAS number 1617-40-9
FEMA number 4290
Molecular formula C8H14O2
Molecular weight 142.2 g/mol
SMILES CC/C=C(\C)C(=O)OCC
InChIKey HYQYCHQAUPHFKX-VOTSOKGWSA-N
PubChem CID 6436311
FDA UNII Q01A9HRA5X
EPA DTXSID DTXSID101301931
Chemical class Ester
Boiling point 173 °C
Flash point 64 °C

Also known as: 2-Pentenoic acid, 2-methyl-, ethyl ester, (2E)-, 2-Pentenoic acid, 2-methyl-, ethyl ester, (E)-, Ethyl (2E)-2-methyl-2-pentenoate, 2-pentenoic acid, 2-methyl-, ethyl ester, ethyl 2-methyl-2-pentenoate, ethyl 2-methylpent-2-en-1-oate, ethyl trans-2-methyl-2-pentenoate, ethyl (2e)-2-methylpent-2-enoate, ethyl (e)-2-methylpent-2-en-1-oate, ethyl 2-methyl-2-pentenoate, (2e)-, ethyl (2e)-2-methyl-2-pentenoate, ethyl 2-methyl-2-pentenoate, trans-.

Can Ethyl (E)-2-methyl-2-pentenoate be labeled natural?

Since Ethyl (E)-2-methyl-2-pentenoate is found in nature, US labeling follows how it was obtained: natural flavor from a natural source and a natural process, artificial when Ethyl (E)-2-methyl-2-pentenoate is synthesized. In the EU and UK the natural claim likewise needs the natural route, while Mercosur and Mexico keep a third class, identical-to-natural, for the synthetic material.

United States
Natural or artificial, by process
European Union and UK
Natural only from natural material
Mercosur and Mexico
Natural or identical-to-natural

How each market defines the classes: natural vs artificial flavor under 21 CFR 101.22.

Regulatory status, with citations

United States

Ethyl (E)-2-methyl-2-pentenoate is FEMA GRAS under FEMA number 4290. It is cited in the Code of Federal Regulations at 21 CFR 172.515.

21 CFR 172.515

European Union and United Kingdom

No EU FL number is on file for Ethyl (E)-2-methyl-2-pentenoate. That is not a finding either way. The Union List covers defined flavouring substances, so natural complex materials are handled as flavouring preparations under Parts B to F and never receive a number, and substances used as additives sit under Regulation 1333/2008 instead. Confirm the position before EU or UK use.

JECFA (WHO / FAO)

JECFA number 1815.

Other US flags

Not on the California Proposition 65 list.

Odor and taste

Odor: Sweet, fruity, peach, tropical, estery.

Where it is used

Ethyl (E)-2-methyl-2-pentenoate is used in beverage, confection, fruit flavors, bakery and desserts, typically as a fruity note.

Structurally similar flavor ingredients

Flavor ingredients with a GRAS determination closest to Ethyl (E)-2-methyl-2-pentenoate by structure. Whether one can replace it is a sensory and regulatory call; the reformulation tool works that through.

MaterialFEMASimilarityOccurrence
Ethyl 2-methyl-4-pentenoate348987%In nature

More esters in this index

Methyl myristate · Neryl isovalerate · Butyl isobutyrate · Butyl salicylate · Butan-3-one-2-yl butanoate · Propyl 2,4-decadienoate

Ethyl (E)-2-methyl-2-pentenoate FAQ

Is Ethyl (E)-2-methyl-2-pentenoate FEMA GRAS?

Yes. The FEMA Expert Panel lists Ethyl (E)-2-methyl-2-pentenoate as GRAS under FEMA number 4290. It is also codified at 21 CFR 172.515.

What are the FEMA and CAS numbers for Ethyl (E)-2-methyl-2-pentenoate?

Ethyl (E)-2-methyl-2-pentenoate is FEMA 4290, CAS 1617-40-9. FEMA files it in the fruity flavor category.

Does Ethyl (E)-2-methyl-2-pentenoate count as natural in the US and the EU?

Ethyl (E)-2-methyl-2-pentenoate occurs in nature, so the label depends on the route: Ethyl (E)-2-methyl-2-pentenoate won from a natural source by a physical, enzymatic or microbiological process is natural flavor in the United States, and synthesized Ethyl (E)-2-methyl-2-pentenoate is artificial. The EU and UK follow the same logic without a middle class; Mercosur and Mexico label synthetic Ethyl (E)-2-methyl-2-pentenoate identical-to-natural.

Is Ethyl (E)-2-methyl-2-pentenoate approved in the EU?

No EU FL number is on file for Ethyl (E)-2-methyl-2-pentenoate. It has a JECFA evaluation (JECFA 1815), which the EU list draws on, but the Union List entry itself should be confirmed before EU use.

Has JECFA evaluated Ethyl (E)-2-methyl-2-pentenoate?

Yes. JECFA number 1815.

How is Ethyl (E)-2-methyl-2-pentenoate described, and where does it show up?

Flavorists describe Ethyl (E)-2-methyl-2-pentenoate as sweet, fruity, peach, tropical, estery. It is used in beverage, confection, fruit flavors, bakery and desserts.

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Sources and attribution. The identity and regulatory facts on this page are taken from the FDA Substances Added to Food inventory, a US government record, which lists this substance as ETHYL TRANS-2-METHYL-2-PENTENOATE under CAS 1617-40-9 and carries its FEMA number, its JECFA flavor number. The inventory is searchable at FDA. FDA records its technical effect as flavoring agent or adjuvant.

A FEMA GRAS conclusion is reached by the Expert Panel of the Flavor and Extract Manufacturers Association of the United States, and the FEMA number names that conclusion. FEMA publishes its own entry for this substance in the FEMA Flavor Library, which is the authoritative record of what the Panel decided and is worth reading alongside this page.

Ambrose Compliance is not affiliated with, endorsed by, or sponsored by FEMA. FEMA and FEMA GRAS are used here as identifiers for a published regulatory determination, not as marks of any relationship between FEMA and Ambrose.

About this page. Facts come from the FDA Substances Added to Food inventory, the Code of Federal Regulations, the EPA TSCA Inventory, the EU Union List, JECFA and the Ambrose database, with FEMA's published determination cited where it applies; parts of the text are written by Ambrose AI, which can make mistakes. Check the cited source before relying on anything here. This is not regulatory or legal advice.