Flavor ingredient regulatory record

Octanal

Octanal is an aldehyde in the citrus family, FEMA GRAS under FEMA number 2797 (CAS 124-13-0). Its odor is citrus, orange, waxy, aldehydic.

FEMA
2797
CAS
124-13-0
JECFA
98
EU FL
05.009
Formula
C8H16O
EC
204-683-8

GRAS status: FEMA GRAS, publication 3. Recorded by FDA in the Substances Added to Food inventory under CAS 124-13-0.

Structure

2D structure of Octanal
Structure of Octanal, C8H16O. Drawn from the canonical SMILES.

Identity

IUPAC name octanal
CAS number 124-13-0
FEMA number 2797
Molecular formula C8H16O
Molecular weight 128.22 g/mol
SMILES CCCCCCCC=O
InChIKey NUJGJRNETVAIRJ-UHFFFAOYSA-N
PubChem CID 454
EC number 204-683-8
FDA UNII XGE9999H19
EPA DTXSID DTXSID3021643
Chemical class Aldehyde
Boiling point 163 °C
Flash point 52 °C

Also known as: Antifoam LF, Caprylaldehyde, Caprylic aldehyde, Octaldehyde, n-Octanal, n-Octylal, n-Caprylaldehyde, n-Octaldehyde, Octanoic aldehyde, Octanaldehyde, Octylaldehyde, n-Octyl aldehyde.

Can Octanal be labeled natural?

Nature makes octanal, which is why the US label turns on process. A natural route gives natural flavor; synthesis gives artificial octanal, same molecule. The EU and UK grant the natural claim only to that natural route; Mercosur and Mexico call synthetic material identical-to-natural.

United States
Natural or artificial, by process
European Union and UK
Natural only from natural material
Mercosur and Mexico
Natural or identical-to-natural

How each market defines the classes: natural vs artificial flavor under 21 CFR 101.22.

Regulatory status, with citations

United States

Octanal is FEMA GRAS under FEMA number 2797. It is cited in the Code of Federal Regulations at 21 CFR 172.515.

21 CFR 172.515

European Union and United Kingdom

Listed on the Union List of flavouring substances as FL 05.009, Annex I Part A under Regulation (EC) 1334/2008, evaluation status approved (JECFA). The UK retains the same list.

Purity. At least 92%; secondary component 4-7% 2-methylheptanal

JECFA (WHO / FAO)

JECFA number 98, evaluated at the 49th meeting in 1997. no safety concern at current levels of intake when used as a flavouring agent. ADI 0 to 0.1 mg/kg body weight.

JECFA monograph

Other US flags

Not on the California Proposition 65 list.

TSCA Inventory status

A flavor ingredient is also an industrial chemical. Octanal appears on the EPA Toxic Substances Control Act Chemical Substance Inventory under CAS 124-13-0, where EPA names it Octanal.

Active in US commerce

EPA designates this substance active, so no Notice of Activity Form B is required before manufacturing. What active and inactive mean.

EPA publishes no regulatory flags on this listing. What the flags mean.

From the EPA non-confidential TSCA Inventory, July 2026 release. EPA also maintains a confidential portion it does not publish. Search the Inventory by CAS number.

Odor and taste

Odor: Citrus, orange, waxy, aldehydic.

Taste: Citrus, orange, slightly soapy.

Where it is used

Octanal is used in orange, citrus and lemon, typically as a citrus note.

Structurally similar flavor ingredients

Flavor ingredients with a GRAS determination closest to Octanal by structure. Whether one can replace it is a sensory and regulatory call; the reformulation tool works that through.

MaterialFEMASimilarityOccurrence
Nonanal278298%In nature
Decanal236296%In nature
trans-Nonenal321394%In nature
cis-5-Octenal374994%In nature
(E)-4-Nonenal430294%In nature

More aldehydes in this index

Decanal · Citronellal · Citral glyceryl acetal · Citral · Lauric aldehyde · Hydroxycitronellal

Octanal FAQ

Does octanal have FEMA GRAS status?

Octanal holds FEMA GRAS status under FEMA number 2797. The Code of Federal Regulations lists it at 21 CFR 172.515.

How do I cite octanal by FEMA or CAS number?

Cite octanal as FEMA 2797 or CAS 124-13-0; both point to the same entry. Its flavor category is citrus.

What does octanal smell and taste like, and where is it used?

The odor of octanal is citrus, orange, waxy, aldehydic. On the palate it is citrus, orange, slightly soapy. Typical uses are orange, citrus and lemon.

What did JECFA conclude about octanal?

JECFA evaluated octanal at the 49th meeting in 1997 under JECFA number 98. The panel concluded: no safety concern at current levels of intake when used as a flavouring agent.

Can octanal be used in the EU and UK?

Yes. FL 05.009 is the Union List entry for octanal, annex I Part A, under Regulation 1334/2008, and the UK keeps the same list.

Can octanal be labeled a natural flavor?

The process decides for octanal. It occurs in nature, so a natural-source, natural-process material is natural flavor in the US and synthetic octanal is artificial. The EU and UK grant the natural claim only to that natural route; Mercosur and Mexico call synthetic material identical-to-natural.

Ingredient lookup

Check an ingredient

Start typing to search the ingredient corpus.

Or browse every ingredient page, A to Z.

Guides: What Is FEMA GRAS? · Natural vs artificial · Filing a GRAS notification

Check Octanal in a formula

Screened against FEMA GRAS, 21 CFR and EU rules as you build. Free to start.

Sources and attribution. The identity and regulatory facts on this page are taken from the FDA Substances Added to Food inventory, a US government record, which lists this substance as OCTANAL under CAS 124-13-0 and carries its FEMA number, its JECFA flavor number and its 21 CFR citations. The inventory is searchable at FDA. FDA records its technical effect as flavoring agent or adjuvant.

A FEMA GRAS conclusion is reached by the Expert Panel of the Flavor and Extract Manufacturers Association of the United States, and the FEMA number names that conclusion. FEMA publishes its own entry for this substance in the FEMA Flavor Library, which is the authoritative record of what the Panel decided and is worth reading alongside this page.

Ambrose Compliance is not affiliated with, endorsed by, or sponsored by FEMA. FEMA and FEMA GRAS are used here as identifiers for a published regulatory determination, not as marks of any relationship between FEMA and Ambrose.

About this page. Facts come from the FDA Substances Added to Food inventory, the Code of Federal Regulations, the EPA TSCA Inventory, the EU Union List, JECFA and the Ambrose database, with FEMA's published determination cited where it applies; parts of the text are written by Ambrose AI, which can make mistakes. Check the cited source before relying on anything here. This is not regulatory or legal advice.