Flavor ingredient regulatory record

Allyl heptanoate

Allyl heptanoate is an ester in the fruity family, FEMA GRAS under FEMA number 2031 (CAS 142-19-8). Its odor is sweet, fruity, tropical, peach, floral.

FEMA
2031
CAS
142-19-8
JECFA
4
EU FL
09.097
Formula
C10H18O2
EC
205-527-1

GRAS status: FEMA GRAS, publication 3. Recorded by FDA in the Substances Added to Food inventory under CAS 142-19-8.

Structure

2D structure of Allyl heptanoate
Structure of Allyl heptanoate, C10H18O2. Drawn from the canonical SMILES.

Identity

IUPAC name prop-2-enyl heptanoate
CAS number 142-19-8
FEMA number 2031
Molecular formula C10H18O2
Molecular weight 170.25 g/mol
SMILES C=CCOC(=O)CCCCCC
InChIKey SJWKGDGUQTWDRV-UHFFFAOYSA-N
PubChem CID 8878
EC number 205-527-1
FDA UNII AU4CYG9V68
EPA DTXSID DTXSID3044754
Chemical class Ester
Boiling point 207 °C
Flash point 89 °C

Also known as: Heptanoic acid, 2-propen-1-yl ester, Heptanoic acid, allyl ester, Heptanoic acid, 2-propenyl ester, Allyl enanthate, Allyl heptoate, Allyl heptylate, 2-Propenyl heptanoate, NSC 20969, allyl heptylate, allyl enanthate, 2-propenyl heptanoate, allyl heptoate.

Can Allyl heptanoate be labeled natural?

The process decides for allyl heptanoate. It occurs in nature, so a natural-source, natural-process material is natural flavor in the US and synthetic allyl heptanoate is artificial. The EU and UK grant the natural claim only to that natural route; Mercosur and Mexico call synthetic material identical-to-natural.

United States
Natural or artificial, by process
European Union and UK
Natural only from natural material
Mercosur and Mexico
Natural or identical-to-natural

How each market defines the classes: natural vs artificial flavor under 21 CFR 101.22.

Regulatory status, with citations

United States

Allyl heptanoate is FEMA GRAS under FEMA number 2031. It is cited in the Code of Federal Regulations at 21 CFR 172.515.

21 CFR 172.515

European Union and United Kingdom

Listed on the Union List of flavouring substances as FL 09.097, Annex I Part A under Regulation (EC) 1334/2008, evaluation status approved (JECFA). The UK retains the same list.

JECFA (WHO / FAO)

JECFA number 4, evaluated at the 46th meeting in 1996. 0-0.15 mg/kg bw (1990). ADI 0 to 0.15 mg/kg body weight.

JECFA monograph

Other US flags

Not on the California Proposition 65 list.

TSCA Inventory status

A flavor ingredient is also an industrial chemical. Allyl heptanoate appears on the EPA Toxic Substances Control Act Chemical Substance Inventory under CAS 142-19-8, where EPA names it Heptanoic acid, 2-propen-1-yl ester.

Active in US commerce

EPA designates this substance active, so no Notice of Activity Form B is required before manufacturing. What active and inactive mean.

EPA publishes no regulatory flags on this listing. What the flags mean.

From the EPA non-confidential TSCA Inventory, July 2026 release. EPA also maintains a confidential portion it does not publish. Search the Inventory by CAS number.

Odor and taste

Odor: Sweet, fruity, tropical, peach, floral.

Where it is used

Allyl heptanoate is used in beverage, confection, fruit flavors, bakery and ice cream, typically as a fruity note.

Structurally similar flavor ingredients

Flavor ingredients with a GRAS determination closest to Allyl heptanoate by structure. Whether one can replace it is a sensory and regulatory call; the reformulation tool works that through.

MaterialFEMASimilarityOccurrence
Allyl hexanoate203295%In nature
1-Octen-3-yl acetate358290%In nature
1-Octen-3-yl butyrate361288%In nature
10-Undecen-2-one440674%In nature
Propyl heptanoate294870%In nature

More esters in this index

3-n-Butylphthalide · Glyceryl monooleate · Ethyl 3-octenoate · Butyl phenylacetate · cis-Hexenyl propionate · Bornyl butyrate

Allyl heptanoate FAQ

Is allyl heptanoate FEMA GRAS?

Yes. The FEMA Expert Panel lists allyl heptanoate as GRAS under FEMA number 2031. The Code of Federal Regulations lists it at 21 CFR 172.515.

What are the FEMA and CAS numbers for allyl heptanoate?

Allyl heptanoate is FEMA 2031, CAS 142-19-8. Its flavor category is fruity.

How is allyl heptanoate described, and where does it show up?

Flavorists describe allyl heptanoate as sweet, fruity, tropical, peach, floral. It is used in beverage, confection, fruit flavors, bakery and ice cream.

What did JECFA conclude about allyl heptanoate?

JECFA evaluated allyl heptanoate at the 46th meeting in 1996 under JECFA number 4. The panel concluded: 0-0.15 mg/kg bw (1990).

Is allyl heptanoate on the EU Union List?

Yes. FL 09.097 is the Union List entry for allyl heptanoate, annex I Part A, under Regulation 1334/2008, and the UK keeps the same list.

Does allyl heptanoate count as natural in the US and the EU?

Nature makes allyl heptanoate, which is why the US label turns on process. A natural route gives natural flavor; synthesis gives artificial allyl heptanoate, same molecule. In the EU and UK the natural claim likewise needs the natural route, while Mercosur and Mexico keep a third class, identical-to-natural, for the synthetic material.

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Sources and attribution. The identity and regulatory facts on this page are taken from the FDA Substances Added to Food inventory, a US government record, which lists this substance as ALLYL HEPTANOATE under CAS 142-19-8 and carries its FEMA number, its JECFA flavor number. The inventory is searchable at FDA. FDA records its technical effect as flavoring agent or adjuvant.

A FEMA GRAS conclusion is reached by the Expert Panel of the Flavor and Extract Manufacturers Association of the United States, and the FEMA number names that conclusion. FEMA publishes its own entry for this substance in the FEMA Flavor Library, which is the authoritative record of what the Panel decided and is worth reading alongside this page.

Ambrose Compliance is not affiliated with, endorsed by, or sponsored by FEMA. FEMA and FEMA GRAS are used here as identifiers for a published regulatory determination, not as marks of any relationship between FEMA and Ambrose.

About this page. Facts come from the FDA Substances Added to Food inventory, the Code of Federal Regulations, the EPA TSCA Inventory, the EU Union List, JECFA and the Ambrose database, with FEMA's published determination cited where it applies; parts of the text are written by Ambrose AI, which can make mistakes. Check the cited source before relying on anything here. This is not regulatory or legal advice.