Flavor ingredient regulatory record

1-p-Menthen-9-yl acetate

1-p-Menthen-9-yl acetate is an ester in the fruity family, FEMA GRAS under FEMA number 3566 (CAS 28839-13-6). Its odor is sweet, fruity, citrus, apple, estery.

FEMA
3566
CAS
28839-13-6
JECFA
972
EU FL
09.615
Formula
C12H20O2
EC
249-266-1

GRAS status: FEMA GRAS, publication 11. Recorded by FDA in the Substances Added to Food inventory under CAS 28839-13-6.

Structure

2D structure of 1-p-Menthen-9-yl acetate
Structure of 1-p-Menthen-9-yl acetate, C12H20O2. Drawn from the canonical SMILES.

Identity

IUPAC name 2-(4-methylcyclohex-3-en-1-yl)propyl acetate
CAS number 28839-13-6
FEMA number 3566
Molecular formula C12H20O2
Molecular weight 196.29 g/mol
SMILES CC(=O)OCC(C)C1CC=C(C)CC1
InChIKey QUHIXSUMNSRNNP-UHFFFAOYSA-N
PubChem CID 527144
EC number 249-266-1
FDA UNII QLZ5AAU20V
EPA DTXSID DTXSID40865453
Chemical class Ester
Boiling point 232 °C
Flash point 102 °C

Also known as: 3-Cyclohexene-1-ethanol, β,4-dimethyl-, 1-acetate, p-Menth-1-en-9-ol, acetate, 3-Cyclohexene-1-ethanol, β,4-dimethyl-, acetate, p-Menth-1-en-9-yl acetate, p-menth-1-en-9-yl acetate, 9-acetoxy-1-p-menthene, p-menth-1-en-9-ol, acetate, 1-para-menthen-9-yl acetate, beta,4-dimethyl-3-cyclohexene-1-ethyl acetate, 3-cyclohexene-1-ethanol, beta,4-dimethyl-, acetate, 1-p-menthen-9-yl acetate [fhfi], 3-cyclohexene-1-ethanol, .beta.,4-dimethyl-, acetate.

Can 1-p-Menthen-9-yl acetate be labeled natural?

Since 1-p-Menthen-9-yl acetate is found in nature, US labeling follows how it was obtained: natural flavor from a natural source and a natural process, artificial when 1-p-Menthen-9-yl acetate is synthesized. The EU and UK grant the natural claim only to that natural route; Mercosur and Mexico call synthetic material identical-to-natural.

United States
Natural or artificial, by process
European Union and UK
Natural only from natural material
Mercosur and Mexico
Natural or identical-to-natural

How each market defines the classes: natural vs artificial flavor under 21 CFR 101.22.

Regulatory status, with citations

United States

1-p-Menthen-9-yl acetate is FEMA GRAS under FEMA number 3566. It is cited in the Code of Federal Regulations at 21 CFR 172.515.

21 CFR 172.515

European Union and United Kingdom

Listed on the Union List of flavouring substances as FL 09.615, Annex I Part A under Regulation (EC) 1334/2008, evaluation status approved (EFSA). The UK retains the same list.

JECFA (WHO / FAO)

JECFA number 972, evaluated at the 59th meeting in 2002. No safety concern at current levels of intake when used as a flavouring agent.

JECFA monograph

Other US flags

Not on the California Proposition 65 list.

Odor and taste

Odor: Sweet, fruity, citrus, apple, estery.

Where it is used

1-p-Menthen-9-yl acetate is used in beverage, confection, fruit flavors, ice cream and baked goods, typically as a fruity note.

Structurally similar flavor ingredients

Flavor ingredients with a GRAS determination closest to 1-p-Menthen-9-yl acetate by structure. Whether one can replace it is a sensory and regulatory call; the reformulation tool works that through.

MaterialFEMASimilarityOccurrence
p-Mentha-1,8-dien-7-yl acetate356180%In nature
Carvyl propionate225175%In nature
Dihydrocarvyl acetate238072%In nature
alpha-Terpinyl acetate304770%In nature
1-Phenyl-3-methyl-3-pentanol288365%In nature

More esters in this index

(E,Z)-3,6-Nonadien-1-ol acetate · Ethyl phenylacetate · Propyl cinnamate · p-Mentha-1,8-dien-7-yl acetate · 3-Hexenyl 3-methylbutanoate · Dihydrocarvyl acetate

1-p-Menthen-9-yl acetate FAQ

Is 1-p-Menthen-9-yl acetate on the FEMA GRAS list?

It is. FEMA number 3566 covers 1-p-Menthen-9-yl acetate. It is also codified at 21 CFR 172.515.

What is the FEMA number for 1-p-Menthen-9-yl acetate?

The FEMA number for 1-p-Menthen-9-yl acetate is 3566 and its CAS registry number is 28839-13-6. FEMA files it in the fruity flavor category.

Is 1-p-Menthen-9-yl acetate natural or artificial?

1-p-Menthen-9-yl acetate occurs in nature, so the label depends on the route: 1-p-Menthen-9-yl acetate won from a natural source by a physical, enzymatic or microbiological process is natural flavor in the United States, and synthesized 1-p-Menthen-9-yl acetate is artificial. In the EU and UK the natural claim likewise needs the natural route, while Mercosur and Mexico keep a third class, identical-to-natural, for the synthetic material.

Is 1-p-Menthen-9-yl acetate approved in the EU?

1-p-Menthen-9-yl acetate is on the EU Union List of flavouring substances as FL 09.615 (Annex I Part A) under Regulation 1334/2008.

Has JECFA evaluated 1-p-Menthen-9-yl acetate?

Yes. JECFA number 972, evaluated at the 59th meeting in 2002. Conclusion: No safety concern at current levels of intake when used as a flavouring agent.

What is 1-p-Menthen-9-yl acetate used for?

1-p-Menthen-9-yl acetate is described as sweet, fruity, citrus, apple, estery. It shows up in beverage, confection, fruit flavors, ice cream and baked goods.

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Sources and attribution. The identity and regulatory facts on this page are taken from the FDA Substances Added to Food inventory, a US government record, which lists this substance as 1-P-MENTHEN-9-YL ACETATE under CAS 28839-13-6 and carries its FEMA number, its JECFA flavor number and its 21 CFR citations. The inventory is searchable at FDA. FDA records its technical effect as flavoring agent or adjuvant.

A FEMA GRAS conclusion is reached by the Expert Panel of the Flavor and Extract Manufacturers Association of the United States, and the FEMA number names that conclusion. FEMA publishes its own entry for this substance in the FEMA Flavor Library, which is the authoritative record of what the Panel decided and is worth reading alongside this page.

Ambrose Compliance is not affiliated with, endorsed by, or sponsored by FEMA. FEMA and FEMA GRAS are used here as identifiers for a published regulatory determination, not as marks of any relationship between FEMA and Ambrose.

About this page. Facts come from the FDA Substances Added to Food inventory, the Code of Federal Regulations, the EPA TSCA Inventory, the EU Union List, JECFA and the Ambrose database, with FEMA's published determination cited where it applies; parts of the text are written by Ambrose AI, which can make mistakes. Check the cited source before relying on anything here. This is not regulatory or legal advice.